Search results for " heat capacity"
showing 7 items of 7 documents
Heat Capacity and Entanglement Measure in a simple two-qubit model
2011
A simple two-qubit model showing Quantum Phase Transitions as a consequence of ground state level crossings is studied in detail. Using the Concurrence of the system as an entanglement measure and heat capacity as a marker of thermodynamical properties, an analytical expression giving the latter in terms of the former is obtained. A protocol allowing an experimental measure of entanglement is then presented and compared with a related proposal recently reported by Wie\'sniak, Vedral and Brukner
Prediction of ionic liquid's heat capacity by means of their in silico principal properties
2016
The in silico principal properties (PPs) of ionic liquids (ILs), derived by means of the VolSurf+ approach, were used to develop a Partial Least Squares (PLS) model able to find a quantitative correlation among IL descriptors (accounting for both cationic and anionic structural features) and heat capacity values, providing affordable predictions validated by experimental Cp measurements for an external set of ILs. In silico predictions allowed the selection of a limited number of structurally different ILs with similar Cp values, providing the possibility to select an optimal IL according to efficiency, as well as to environmental and economic sustainability. The present general procedure, …
Thermal Parameters Measurements of High-Rise Building Envelope
2016
In buildings, to ensure the thermal comfort of the occupants and to keep the energy consumption as low as possible, a correct design of the thermal system is necessary. To do so, an appropriate determination of the thermo-physical properties of the wall materials is needed, particularly; new light-weight building technologies are widely used in the construction of the building envelope. One of these parameters, particularly important in Mediterranean climatic dynamic conditions is the heat capacity, due to the presence of the sun’s energy contribution in hot and cold seasons. The value of the heat capacity in such like materials is typically quite different from the declared parameter, obta…
Thermal characterization of insulating materials
2018
Abstract The strict energy saving standards are based on the declared values of the materials, i.e. U-value, thermal conductivity or thermal capacity. To this end, proper knowledge of the thermophysical properties of the wall components is needed, especially with regard to new lightweight technologies that are being used in building construction/refurbishment, under the dynamic conditions of the Mediterranean climate, where one of most important parameters of building materials is their heat capacity because of the influence of solar radiation energy. With this regard, the actual heat capacity value, obtained in laboratory tests, is typically quite different from the nominal one. So, this p…
Entanglement and heat capacity in a two-atom Bose–Hubbard model
2012
Abstract We show that a two-atom Bose–Hubbard model exhibits three different phases in the behavior of thermal entanglement in its parameter space. These phases are demonstrated to be traceable back to the existence of level crossings in the ground state of the same system. Significant similarities between the behaviors of thermal entanglement and heat capacity in the parameter space are brought to light thus allowing to interpret the occurrence and the meaning of all these three phases.
Effects of solarisation on soil thermal-physical properties under different soil treatments: A review
2020
Solarisation technology allows for improving soil quality as well as crop productivity. The influence of the properties and method of use of plastic materials used to cover soils, such as the number and thickness of layers, and colour of the material, significantly alters soil thermal-physical properties. These effects can be managed and modified to increase solarisation efficiency by achieving a decrease in vapour movement between the soil surface and the atmosphere. Also, soil solarisation establishes microclimates that increase the effectiveness of fertilisers, thus modifying the soil thermal-physical properties. However, there is a lack of complete and general overview of this widely us…
Volume and heat capacity studies to evidence interactions between cyclodextrins and nicotinic acid in water
2008
Density and heat capacity of the water+cyclodextrin (CD), water+nicotinic acid (NA) and water+CD+NA mixtures were determined at 298.15 K. CDs with different cavity size and alkylation were selected. From the experimental data the apparent molar properties were calculated. Assuming the formation of inclusion complexes of 1:1 stoichiometry, these properties were modeled and provided the stability constants of CD/NA inclusion complexes and the corresponding property change. The binding of NA with the smallest sized alpha-cyclodextrin (alpha-CD) generates more stable complexes accompanied by the lower volume and the heat capacity changes. These results are in agreement with earlier proposed bin…